SYNTHESIS AND CHARACTERIZATION OF SOME TRANSITION METAL COMPLEXES WITH SULPHUR CONTAINING LIGAND
*Abhishek Kumar Mishra and Mohammad Aslam
ABSTRACT
The ligand was prepared by reacting piperdine with carbon disulphide
and sodium hydroxide. Its transition metal complexes were synthesized
by substitution reaction by reacting sodium salt of piperdine
dithiocarbamate with salt solutions. These complexes were
characterized by elemental analysis and spectral studies. Based upon
these analyses, it was confirmed that In all these complexes
dithiocarbamate group is coordinated symmetrically as bidentate
ligand. In all these complexes the metal is either tetra or hexacoordinated
giving square planer or octahedral geometry.
Keywords: Dithiocarbamate, metal complexes, symmetrical coordination, square planer and octahedral geometry.
[Full Text Article]