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Abstract

NOVEL AROMATIC SYSTEM-III: 2,3-DIMETHYL BENZOCYCLOHEPTEN-5-ONE

B. Srinivasulu*

ABSTRACT

The use of lithium chloride in boiling dimethylforamide has been shown to give high yields of 2,3-dimethyl benzocyclohepten-5-one (4) from 2,3-dimethyl-6,6-dibromo-6,7,8,9-tetrahydrobenzocyclohepten-5- one (3). Similar elimination occurs from 2,3-dimethyl-6,9-dibromo- 6,7,8,9-tetrahydrobenzo- cyclohepten-5-one (5) to give (4).

Keywords: Lithium chloride, dimethylformamide, NBS, cyclohepten-5-one.


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