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Abstract

FIBRAL FORMING SYNTHETIC POLYETHERS FROM ISOMANNIDE AND GROUP 4 METALLOCENE DICHLORIDES AND ORGANOTIN DIHALIDES

Charles E. Carraher, Jr.*, Michael R. Roner, Jessica Frank, Loretta Chen and Tiasha Arnold

Abstract

Polymers were formed in moderate yield and chain length from the interfacial polymerization of isomannide and Group 4 metallocene dichlorides and organotin dihalides. These polymers possess a rigid backbone promoting the formation of fibrils. The polymers spontaneously formed flexible fibrils with aspect ratios of over 1000. The products were synthesized from commercially available materials, so reproduction should be straight forward.

Keywords: Isomannide, Group 4 metallocene polymers, titanocene polymers, zirconium polymers, hafnocene polymers, organotin polymers, spontaneous fibril formation, interfacial polymerization.


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