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Abstract

REACTIVITY RATIOS AND ANTIMICROBIAL STUDIES OF N-TERTAMYLACRYLAMIDE AND 8-QUINOLINYL ACRYLATE COPOLYMERS

P. Vimala and P. Pazhanisamy*

Abstract

Copolymers of N-tert-amyl acrylamide (NTA) and 8-quinolinyl acrylate (8-QA) were prepared by free radical polymerization in Methanol Water (3:1) at 600C using AIBN as an initiator. (Scheme 1) The copolymer compositions were determined by 1H-NMR analysis. The reactivity ratios of monomers were determined by Fineman-Ross (FR) (r1 = 0.83 and r2 = 2.0), Kelen-Tudos (KT) (r1 = 0.83and r2 = 2.0). The r1.r2 = 1.66 indicated the formation of random copolymers.Tg found to increasing feed content of QA. The antimicrobial studies showed that the copolymers are active against both Bacteria and Fungi.

Keywords: N-tert-amylacrylamide; 8-quinolinylacrylate; reactivity ratios; copolymer composition.


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