Abstract

DIELECTRIC STUDIES OF THE TERNARY MIXTURES OF AMINES WITH DECANOL IN CARBON TETRACHLORIDE SYSTEMS

S. Aram, H. B. Ramalingam and P. Krishnamurthi

Abstract

The hydrogen bonded complexes involving primary amines (propyl amine, butyl amine and pentyl amine) and decanol in carbon tetrachloride were studied at 301k. The dipole moment of the complex obtained from the dielectric measurements using by Huysken’s method based on Onsager theory. The dipolar increment and enthalpy changes during fond formation were evaluated from the complex dipole moment. The results were interpreted in terms of interactions. The and values indicate the interaction due to polarization only

Keywords: Dielectric constant, H-bonding, dipole moment, dipolar increment, Enthalpy.